Navigating Global Azole Constraint with Engineered Copper Passivation (ECP) Technology

Date: Thursday, October 20, 2022 // Time: 2:00 - 3:00 PM EDT

Since the 1950’s, industrial water treatment has primarily used benzotriazole derivatives for yellow metal (copper, copper nickel, and admiralty heat exchangers) corrosion control. Azole-based technology do have drawbacks and limitations. The main negative aspects include elevated aquatic toxicity, generation of adsorbable organic halides (AOX) and loss of metal surface passivation when exposed to oxidizers. More recently, material availability is another limitation that has complicated traditional azole technology use. Supply chain issues around raw materials, government-imposed tariffs and shipping delays have affected supply and driven costs up significantly, prompting end users to seek out new technologies that reduce their dependency on this technology.

State of the art surface science technology (XPS, ToF-SIMS, TEM) has aided in the understanding of how passivation films are constructed at a molecular level on metal surface. This has allowed for the development of a novel “engineered copper passivation” (ECP) protective system of components that form an electrically insulating barrier to inhibit corrosion. The technology works by forming a dynamic “co-film” that integrates low level azoles, patent pending chemistry, and various salt colloids present in cycled water chemistry. This solution significantly reduces end user’s dependency on azole chemistry, easing the pain brought on by supply chain issues while improving asset protection and environmental compliance.

MODERATOR:


Charles Civiletto
North America Technical Director, Veolia


Chuck Civiletto has been with Veolia – Water Technologies & Solutions for 18 years. He started with the business as a Chemical Engineering Co-op from Northeastern University. He has held various commercial roles, including area manager in New England and regional manager in Ohio Valley, gaining exposure and experience across a wide range of industries and applications. In his current role as North America Technical Director for the Chemical Monitoring & Solutions team, he leads our team of product application experts for the cooling, boiler, and industrial process product lines. 

 

PRESENTER:


Eric Zubovic
Senior Product Applications Engineer - Cooling, Veolia


Eric has spent the majority of his 25-year water treatment career working in the field. During his tenure, he has successfully held several positions within the organization including account manager, technical manager, area manager, and senior regional engineer. Eric has co-authored several technical papers for professional organizations like TAPPI, AISE, Eastern States Coke and Blast Furnace Society, Clearwater Clean Coal Conference, AIChE and the International Water Conference. Eric holds degrees in chemistry, mathematics, chemical engineering, and business administration.



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